Three novel aromatic imidoaryl bisphenols 6a-c with bulky groups of varying
size on the pendent phenyl ring have been synthesized from 3,8-bis(4-hydro
xyphenyl)-N-phenyl-1,2-naphthalimide 1a. Poly(imidoaryl ether)s were synthe
sized in dipolar aprotic solvents by reacting the monomers with activated d
ifluoro compounds. Glass transition temperatures (T-g) for the polymers are
in the range 265.9-315.0 degreesC, and they exhibit a range of colors from
yellow to red. The highest T-g and 5% weight loss temperature of these pol
ymers were 315 and 496 degreesC, respectively. Most of the polymers are sol
uble in chloroform at room temperature. The UV-vis absorption spectra of po
lymers 11ae, 11be and 16 were recorded in chloroform. Polymer 16 has the mo
st intense absorption peaks (above 300 nm) at 492 and 528 nm, respectively,
while the fluorescent spectrum of polymer 16 shows several peaks at 428, 5
39, 577 and 625 nm, respectively, when excited at 350 nm. Copyright (C) 200
1 John Wiley & Sons, Ltd.