PERSISTENCE LENGTH OF ISOTACTIC POLY(HYDROXY BUTYRATE)

The persistence length of isotactic poly(hydroxy butyrate) was measure d using small-angle neutron scattering. The value obtained from these measurements reflects a high degree of local chain persistence. If thi s local persistence is accounted for, scattering from these chains can be globally fit with Gaussian scaling. A global scattering function, the unified equation, is used, which decomposes the chain structure in to two levels, one corresponding to the Gaussian regime and one to the persistence regime. The persistence length obtained using this global scattering function is compared to that obtained using the graphical approach of Kratky and Pored with good agreement. Additionally, the gl obal fitting approach of Sharp and Bloomfield is also considered. The Kratky and the Sharp and Bloomfield approaches appear to yield differe nt values for the persistence length. Additionally, the Sharp and Bloo mfield function does not allow inspection of the component parts of th e fit. One advantage of both global functions is that the level of sta tistical confidence in the persistence length can be determined in a l east-squares fit. Another advantage is the removal of ambiguity concer ning an apparent regime of non-Gaussian scaling between the persistenc e scaling regime and the Gaussian regime.