Vn. Vertoprakhov et Sa. Krupoder, Preparation of thin copper films from the vapour phase of volatile copper(I) and copper(II) derivatives by the CVD method, USP KH, 69(12), 2000, pp. 1149-1177
The main chemical aspects of the preparation of thin copper films from vapo
urs of volatile univalent and divalent, copper derivatives used as precurso
rs in the MOCVD technique, are considered. Data on the methods of synthesis
and properties of various types of these compounds are generalised and des
cribed systematically. The possible decomposition mechanisms of copper comp
ounds under CVD conditions are discussed. The prospects for the use of MOCV
D technology for the preparation of thin copper films in the integrated cir
cuits of microelectronic devices are outlined.