Preparation of thin copper films from the vapour phase of volatile copper(I) and copper(II) derivatives by the CVD method

Citation
Vn. Vertoprakhov et Sa. Krupoder, Preparation of thin copper films from the vapour phase of volatile copper(I) and copper(II) derivatives by the CVD method, USP KH, 69(12), 2000, pp. 1149-1177
Citations number
432
Categorie Soggetti
Chemistry
Journal title
USPEKHI KHIMII
ISSN journal
00421308 → ACNP
Volume
69
Issue
12
Year of publication
2000
Pages
1149 - 1177
Database
ISI
SICI code
0042-1308(2000)69:12<1149:POTCFF>2.0.ZU;2-F
Abstract
The main chemical aspects of the preparation of thin copper films from vapo urs of volatile univalent and divalent, copper derivatives used as precurso rs in the MOCVD technique, are considered. Data on the methods of synthesis and properties of various types of these compounds are generalised and des cribed systematically. The possible decomposition mechanisms of copper comp ounds under CVD conditions are discussed. The prospects for the use of MOCV D technology for the preparation of thin copper films in the integrated cir cuits of microelectronic devices are outlined.