Crystal structure of 1,2-bis(diphenylphosphinoxy)-ethane rhodium(I)-norborna-2,5-diene tetrafluoroborate, C33H32BF4O2P2Rh, and of 1,2-bis(diphenylphosphinoxy)-ethane rhodium(I)-(Z,Z)-cycloocta-1,5-diene tetrafluoroborate, C34H36BF4O2P2Rh center dot C4H8O center dot/4CH(2)Cl(2)

Authors
Kempe, R Spannenberg, A Heller, D Kadyrov, R Fehring, V
Citation
R. Kempe et al., Crystal structure of 1,2-bis(diphenylphosphinoxy)-ethane rhodium(I)-norborna-2,5-diene tetrafluoroborate, C33H32BF4O2P2Rh, and of 1,2-bis(diphenylphosphinoxy)-ethane rhodium(I)-(Z,Z)-cycloocta-1,5-diene tetrafluoroborate, C34H36BF4O2P2Rh center dot C4H8O center dot/4CH(2)Cl(2), Z KRIST-NEW, 216(1), 2001, pp. 157-160
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES
ISSN journal
14337266 → ACNP
Volume
216
Issue
1
Year of publication
2001
Pages
157 - 160
Database
ISI
SICI code
1433-7266(2001)216:1<157:CSO1R>2.0.ZU;2-3
Abstract
C33H32BF4O2P2Rh; triclinic, P (1) over bar (No. 2), a = 9.342(2) Angstrom, b = 10.279(3) Angstrom, c = 16.964(3) Angstrom, alpha = 74.88(2)degrees, be ta = 82.13(2)degrees, gamma = 83.63(2)degrees, V= 1552.9 Angstrom (3), Z = 2, R-gt(F) = 0.042, WRobs(F-2) = 0.095, T = 200 K. C38.25H44.50BCl0.50F4O3P2Rh, monoclinic, P12(1)/n1 (No. 14), a = 9.629(2) A ngstrom, b = 24.925(5) Angstrom, c = 16.639(3) Angstrom, beta = 92.31(3)deg rees, V= 3990.2 Angstrom (3), Z = 4, R-gt(F) = 0.060, wR(obs)(F-2) = 0.170, T= 200 K.