The diffusional mobilities of Cr, Ni, and Si in fee Cr-Ni-Si alloys have be
en assessed as a function of temperature and composition by means of a CALP
HAD (CALculation of PHAse Diagrams) type of procedure. Optimized kinetic pa
rameters are presented. Comparisons between the calculated and measured dif
fusion coefficients show that most of the experimental information is satis
factorily accounted for by the present modeling. The obtained parameters ca
n predict reasonably concentration profiles in binary Ni-Si and ternary Cr-
Ni-Si diffusion couples.