We demonstrate wide tunability, from green to near infrared, of the electro
luminescence emission of substituted oligothiophene compounds. The compound
s are characterized by high chemical stability, electron affinities up to 3
.1 eV and photoluminescence efficiencies up to 70%. These characteristics m
ake these materials excellent candidates for application in light-emitting
diodes. We obtain low turn-on voltage devices with electroluminescence effi
ciency up to 0.2%, more than one order of magnitude larger than the values
reported for unsubstituted oligothiophene compounds. (C) 2001 American Inst
itute of Physics.