Monodentate, didentate, and tridentate ligation of a Schiff-base ligand ina tetranuclear zinc(II) complex

Authors
Mikuriya, M Ikemi, S Lim, JW
Citation
M. Mikuriya et al., Monodentate, didentate, and tridentate ligation of a Schiff-base ligand ina tetranuclear zinc(II) complex, B CHEM S J, 74(1), 2001, pp. 99-100
Citations number
14
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
74
Issue
1
Year of publication
2001
Pages
99 - 100
Database
ISI
SICI code
0009-2673(200101)74:1<99:MDATLO>2.0.ZU;2-Y
Abstract
A tetranuclear zinc(II) complex with 2,6-bis(salicylideneaminomethyl)-4-met hylphenol (H3L), [Zn-4(L)(2)(pz)(2)]. 2CH(3)CN (Hpz = pyrazole), was synthe sized and characterized by H-1 NMR spectroscopy and a single-crystal X-ray diffraction method. Each Schiff-base L3- acts as a monodentate, a didentate , and a tridentate ligand for four zinc atoms to form a Z-shaped tetranucle ar structure.