Synthesis and structural characterization of tetranuclear zinc(II) complexes with a linear array

Authors
Mikuriya, M Ikenoue, S Nukada, R Lim, JW
Citation
M. Mikuriya et al., Synthesis and structural characterization of tetranuclear zinc(II) complexes with a linear array, B CHEM S J, 74(1), 2001, pp. 101-102
Citations number
13
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
74
Issue
1
Year of publication
2001
Pages
101 - 102
Database
ISI
SICI code
0009-2673(200101)74:1<101:SASCOT>2.0.ZU;2-T
Abstract
1,3-Bis(salicylideneamino)-2-propanol (H(3)salpro) and 1,3-bis(salicylidene amino)propane (H(2)salpn) react with Zn(ClO4)(2). 6H(2)O and pyrazole (Hpz) to give tetranuclear complexes with a linear Zn-4 array, [Zn-4(Hsalpro)(2) (pz)(2)(Hpz)(2)](ClO4)(2) (1) and [Zn-4(salpn)(2)(pz)(2)(Hpz)(2)] (ClO4)(2) (ClO4)(2) (2), which were characterized by infrared spectra and X-ray crys tallography.