High temperature desulphurization by fine limestone during staged fluidized-bed combustion

Citation
Wz. Khan et Bm. Gibbs, High temperature desulphurization by fine limestone during staged fluidized-bed combustion, CAN J CH EN, 78(6), 2000, pp. 1102-1110
Citations number
36
Categorie Soggetti
Chemical Engineering
Journal title
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
ISSN journal
00084034 → ACNP
Volume
78
Issue
6
Year of publication
2000
Pages
1102 - 1110
Database
ISI
SICI code
0008-4034(200012)78:6<1102:HTDBFL>2.0.ZU;2-1
Abstract
This paper reviews the SO2 emission from a 0.3 m(2) stainless-steel fluidiz ed-bed combustor. Fine coal was premixed with fine limestone and fed pneuma tically under the bed. The SO2 emission was found to depend largely on air staging ratio and bed temperature, which agrees with previous observations. The SO2 emission observed in sorbent-free tests (reported earlier by Khan and Gibbs, 1995) was found to be proportional to the sulphur content of the fuel when limestone was added, the sulphur capture at a fixed Ca/S molar r atio was dependent on oxygen stoichiometry ana bed temperature. Finely size d limestone enhanced the effectivity of the sorbent at low bed temperature and air staging ratio. During staged combustion, the combustion efficiency depended largely on primary air to Coal ratio. Around 90% combustion effici ency was observed at 1 m/s fluidizing velocity which was reduced when fluid izing velocity was increased to 1.5 and 2 m/s. This reduction is due to inc reased elutriation of finer coal particles from the combustor.