Transport phenomena of mass, energy, momentum and electrical charges play a
significant role in proton exchange membrane fuel cells (PEMFCs). In this
study the transport and balance equations are the basis of a simulation mod
el which allows the evaluation of the distribution of the physico-chemical
parameters within the structure of a PEMFC reactor. Model Validation is pre
sented; the validated model is than used to investigate the behaviour of th
e reactor, with particular attention to critical operating conditions. Crit
ical conditions arise in a number of cases: flooding, membrane drying and d
egradation due to temperature peaks are discussed in this paper. (C) 2001 E
lsevier Science Ltd. All rights reserved.