Jc. Yang et al., ANOMALOUS DESORPTION OF COPPER-OXIDE OBSERVED BY IN-SITU TRANSMISSIONELECTRON-MICROSCOPY, MICROSCOPY AND MICROANALYSIS, 3(2), 1997, pp. 121-125
Here we present our observations of an anomalous desorption of copper
oxides from a thin copper film during annealing as observed in an in s
itu transmission electron microscope. The epitaxial cuprous oxide that
formed in air was observed to disappear when the specimen was anneale
d at 300 degrees C and 10(-8) torr. However, removal of the cuprous ox
ide that formed during oxidation in the microscope required both heati
ng at 300 degrees C and simultaneous exposure to methanol vapor.