Wh. Ma et al., Metalorganic chemical vapor deposition of BaTiO3 and SrTiO3 thin films using a single solution source with a non-contact vaporizer, INTEGR FERR, 30(1-4), 2000, pp. 139-148
BaTiO3 and SrTiO3 thin films were prepared by reduced-pressure metalorganic
chemical vapor deposition. Ba(thd)(2)-di-tri, or Sr(thd)(2), and Ti(OPri)(
2)-(thd)(2) were dissolved in diglyme and were delivered by an aerosol-assi
sted non-contact vaporizer. Growth kinetics of the thin films was studied a
s: a function of growth temperature, liquid source concentration and molar
ratio of the metalorganic precursors. The mechanisms of composition control
, crystallization and phase formation of the thin films were investigated o
ver a wide range of stoichiometry.