Solid state features and mechanics properties of PEI/PBT blends

Citation
Fj. Vallejo et al., Solid state features and mechanics properties of PEI/PBT blends, J APPL POLY, 80(6), 2001, pp. 885-892
Citations number
45
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
80
Issue
6
Year of publication
2001
Pages
885 - 892
Database
ISI
SICI code
0021-8995(20010509)80:6<885:SSFAMP>2.0.ZU;2-Y
Abstract
Extrusion-blended and injection-molded PEI/PBT blends were found to be misc ible whatever the composition. The processability of the blends clearly imp roved with the presence of PET. The melt pressure at the exit was seen to b e a parameter as representative of the processability of the blends as the torque of blending. In the blends with 80 and 90% PET, a positive volume of mixing and the maintenance of the crystallinity of PET were seen. However, in the rest of the blends, negative volumes of mixing and important decrea ses in the crystallinity of PET were found. These solid state features gave rise to a ductility similar to that of the pure PEI and to a synergism of the modulus of elasticity and of the yield stress in the 90/10 and 80/20 bl ends such that the values were higher than those of either of the pure comp onents. (C) 2001 John Wiley & Sons, Inc.