ITA
ENG

Sterically hindered iron-porphyrins as catalysts in cyclohexane oxidation.Steric effect of oxygen transfer from PhIO to iron(III)-porphyrins

Authors

Jiang, DX Song, LY Zhu, SJ Gui, MD

Citation

Dx. Jiang et al., Sterically hindered iron-porphyrins as catalysts in cyclohexane oxidation.Steric effect of oxygen transfer from PhIO to iron(III)-porphyrins, J CHEM R-S, (1), 2001, pp. 24-25

Citations number

Categorie Soggetti

Chemistry

Journal title

JOURNAL OF CHEMICAL RESEARCH-S

ISSN journal

03082342 → ACNP

Issue

Year of publication

2001

Pages

24 - 25

Database

ISI

SICI code

0308-2342(200101):1<24:SHIACI>2.0.ZU;2-2

Abstract

Six sterically hindered chloro meso-tetra-ortho-alkylphenylporphinato iron complexes (T(o-R)PPFe(III)Cl, R=Me, Et, n-Pr, n-Bu, i-Pr, t-Bu) were used t o catalyse the monooxygenation of cyclohexane with PhlO. A special steric e ffect of these alkyl substituents R on the catalytic character is proposed on the basis of the results.