E. Danielsson et al., Inductively coupled plasma etch damage in 4H-SiC investigated by Schottky diode characterization, J ELEC MAT, 30(3), 2001, pp. 247-252
Ti Schottky diodes have been used to investigate the damage caused by induc
tively coupled plasma (ICP) etching of silicon carbide. The Schottky diodes
were characterized using TV and CV measurements. An oxidation approach was
tested in order to anneal the damage, and the diode characterization was u
sed to determine the success of the annealing. The barrier height, leakage
current, and ideality factor changed significantly on the sample exposed to
the etch. When the etched samples were oxidized the electrical properties
were recovered and were similar to the unetched reference sample (with oxid
ation temperatures ranging from 900 degreesC up to 1250 degreesC). Annealin
g in nitrogen at 1050 degreesC did not improve the electrical characteristi
cs. A low energy etch showed little influence on the electrical characteris
tics, but since the etch rate was very low the etched depth may not be suff
icient in order to reach a steady state condition for the surface damage.