New inorganic-organic hybrid polymers (ORMOCER (R)s) for integrated optical
and opto-electronic devices were synthesized by sol-gel processing of func
tionalized alkoxysilanes. Process parameters (catalyst, temperature etc.) w
ere optimized to achieve highly reproducible low cost materials which are p
hotopatternable even in higher layer thickness (presently 100 mum within on
e step).
The resulting materials have low optical losses at the most important wavel
engths for telecommunications in the NIR range (0.3 dB/cm at 1320 nm, 0.6 d
B/cm at 1550 nm) and a variety of additional advantageous properties for op
tical interconnection technology and production of opto-electronic devices:
good wetting and adhesion on various substrates (e.g. glass, silicon and s
everal polymers), low processing temperatures (post-bake at 150 degreesC) a
nd high thermal stability (decomposition at 270 degreesC) compared to alter
native opto-polymers for NIR applications. A further advantage is a tunable
refractive index, which can be achieved by mixing different resins.