Magnetic circular dichroism (MCD) spectra have been measured at the Fe and
V L-2,L-3 edges of D0(3)-type (Fe1-xVx)(3) Al in order to investigate their
local magnetic moments and electronic structures. Large MCD is observed at
the Fe L-2,L-3 edges, while the V L-2,L-3 MCD shows relatively small inten
sity with complicated features. Signs of these MCD spectra indicate an anti
ferromagnetic coupling between the magnetic moments on Fe and V. According
to the analysis based on the magneto-optical sum rules, the magnetic moment
decreases with x, but remains fairly large for Fe2VAl, which might arise f
rom its marginally magnetic nature.