The x-ray absorption fine structure (XAFS) of colloidal Au and Au/Ag nanopa
rticles (3.5nm and 20nm mean diameter) in an aqueous solution has been inve
stigated. Size dependent alloying was observed upon deposition of Ag on Au
core. Ag forms distinct layers around the 20 nm Au nanoparticles. In contra
st, random mixing is found for Ag deposited on 3.5nm Au particles.