Effect of the drawing process on the thermal stability of gelatine-polyacrylonitrile graft copolymer fibres

Citation
G. Janowska et T. Mikolajczyk, Effect of the drawing process on the thermal stability of gelatine-polyacrylonitrile graft copolymer fibres, J THERM ANA, 63(3), 2000, pp. 815-822
Citations number
8
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
63
Issue
3
Year of publication
2000
Pages
815 - 822
Database
ISI
SICI code
1388-6150(2000)63:3<815:EOTDPO>2.0.ZU;2-S
Abstract
The thermal stability of gelatine-polyacrylonitrile graft copolymers fibres obtained under various conditions of deformation has been studied. The the rmal properties of examined fibres depend on the synthetic component of the fibre forming material - polyacrylonitrile which appears in the form of gr afted PAN chains and PAN homopolymer. It was stated that the highest therma l stability have those fibres which formation process included two stages o f drawing with the use of deformation close to the maximal values, with the value of the total draw ratio amounting to 691%. It should be supposed tha t with such a drawing process, already in its first stage, are created adva ntageous conditions for the formation of paracrystalline regions to a large r extent and their orientation along the fibre axis.