G. Janowska et T. Mikolajczyk, Effect of the drawing process on the thermal stability of gelatine-polyacrylonitrile graft copolymer fibres, J THERM ANA, 63(3), 2000, pp. 815-822
The thermal stability of gelatine-polyacrylonitrile graft copolymers fibres
obtained under various conditions of deformation has been studied. The the
rmal properties of examined fibres depend on the synthetic component of the
fibre forming material - polyacrylonitrile which appears in the form of gr
afted PAN chains and PAN homopolymer. It was stated that the highest therma
l stability have those fibres which formation process included two stages o
f drawing with the use of deformation close to the maximal values, with the
value of the total draw ratio amounting to 691%. It should be supposed tha
t with such a drawing process, already in its first stage, are created adva
ntageous conditions for the formation of paracrystalline regions to a large
r extent and their orientation along the fibre axis.