Synthesis of phenylene-silylene-vinylene polymer and copolymer by ruthenium-catalyzed silylative cross-coupling reaction

Authors
Majchrzak, M Itami, Y Marciniec, B Pawluc, P
Citation
M. Majchrzak et al., Synthesis of phenylene-silylene-vinylene polymer and copolymer by ruthenium-catalyzed silylative cross-coupling reaction, MACRO RAPID, 22(3), 2001, pp. 202-205
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR RAPID COMMUNICATIONS
ISSN journal
10221336 → ACNP
Volume
22
Issue
3
Year of publication
2001
Pages
202 - 205
Database
ISI
SICI code
1022-1336(20010223)22:3<202:SOPPAC>2.0.ZU;2-B
Abstract
RuH(OAc)(CO)(PPh3)(2) catalyzed silylative cross-coupling polycondensation of 4-(dimethylvinylsilyl)styrene (2) and copolycondensation of 1,4-divinylb enzene (4) with 1,4-bis(dimethylvinylsilyl)benzene (5) appeared to be a nov el synthetic route for highly stereo- and regioselective synthesis of pheny lene(arylene)-silylene-vinylene polymers.