The nature of crosslinking in N-vinylformamide free-radical polymerization

N-Vinylformamide (NVF) free-radical polymerization was found to form polyme r gels at high conversions both in bulk and in solution. the polymerization was conducted at different temperatures, monomer and initiator concentrati ons to show the gelation conditions. Gel fractions and gel swelling ratios were also measured after separating the gel from the polymer samples. In or der to confirm the crosslinking unit, a series of hydrolysis experiments we re conducted on the gel samples. The hydrolysis results showed that the cro sslinks in PNVF gels could be destroyed by alkaline hydrolysis. The most ap propriate explanation to this fact is that crosslinking takes place via the amide group.