Toward organometallic polymers with high directionality containing bis-ortho-chelating ligands

Authors
Back, S Albrecht, M Spek, AL Rheinwald, G Lang, H van Koten, G
Citation
S. Back et al., Toward organometallic polymers with high directionality containing bis-ortho-chelating ligands, ORGANOMETAL, 20(5), 2001, pp. 1024-1027
Citations number
45
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
5
Year of publication
2001
Pages
1024 - 1027
Database
ISI
SICI code
0276-7333(20010305)20:5<1024:TOPWHD>2.0.ZU;2-G
Abstract
The preparation and structure of the rigid rod-like platinum monoacetylide {Pt}C=C-4-C6H2I-1-(CH2NMe2)(2)-2,6) ({Pt}= [Pt(C6H3{Me2NCH2}2-2,6)]) are de scribed. Its oxidative addition to Pd(dba)(2) yields a heterobinuclear {P}C =C{Pd}I complex ({Pd}=[Pd(-4-C6H2{Me2NCH2}(2)-2, 6)](+)); this provides a n ew strategy for the controlled and stepwise construction of rigid rod-like metallopolymers.