Citation
J. Jacob et al., Nickel-mediated selective carbonylation routes to thiocarbamates, ORGANOMETAL, 20(5), 2001, pp. 1028-1031
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333
→ ACNP
Volume
20
Issue
5
Year of publication
2001
Pages
1028 - 1031
Database
ISI
SICI code
0276-7333(20010305)20:5<1028:NSCRTT>2.0.ZU;2-B
Abstract
The nickel complexes Ni(PPh3)(2)X-2 (X = CI Br) have been found to be activ
e for the selective oxidative coupling of aryl thiols with secondary amines
and carbon monoxide to give thiocarbamates. With added oxygen, the reactio
n is catalytic, although competitive oxidation. of the thiol is problematic
.