Resonant multicolor spectroscopy in the photodetachment continuum: Observation of the metastable S-4 state in the negative calcium ion - art. no. 030701
Vv. Petrunin et al., Resonant multicolor spectroscopy in the photodetachment continuum: Observation of the metastable S-4 state in the negative calcium ion - art. no. 030701, PHYS REV A, 6303(3), 2001, pp. 0701
We report the observation of the predicted metastable 4p(3) S-4 state in th
e Ca- ion utilizing a spectroscopic technique based on nonlinear resonant m
ulticolor absorption via an autodetaching state. The binding energy of the
S-4 state is determined to be 586.86(10) meV with respect to the parent Ca(
4p(2) P-3) state, a value less than 3 meV from the predicted one. The lifet
ime of the SS state is determined to be larger than 7 ps.