Theoretical distorted-wave calculations and experimental crossed-beam measu
rements are carried out for the electron-impact ionization of atomic ions i
n the Ga isonuclear sequence. For Ga+ and Ga2+ the indirect process of 3d s
ubshell excitation followed by autoionization is calculated to make a signi
ficant contribution to the total ionization cross section near threshold. F
or Ga3+, Ga4+, and Ga5+ the total ionization cross section is calculated to
be dominated by direct ionization of the 3d subshell. For Ga6+, Ga7+, Ga8, and Ga9+ the indirect process of 3p subshell excitation followed by autoi
onization is calculated to make a sizable contribution to the total ionizat
ion cross section. The distorted-wave predictions for the Ga ions are gener
ally confirmed by the reasonable agreement found between theory and experim
ent along the isonuclear sequence.