M. Eddrief et al., Epitaxial growth and magnetic properties of Fe(111) films on Si(111) substrate using a GaSe(001) template - art. no. 094428, PHYS REV B, 6309(9), 2001, pp. 4428
We report the growth of Fe(111) overlayers on unstrained GaSe(001) epitaxie
d on a Si(111)-H terminated substrate. The GaSe prevents chemical reaction
between Fe and Si and enables the achievement of fully relaxed Fe films abo
ve monolayer coverage, despite the 8% lattice mismatch between Fe and GaSe.
The evolution of the magnetic properties and chemical reactivity of the ir
on layer has been studied as a function of thickness. The reduction of magn
etization for very thin Fe films has been correlated with a self-limited so
lid-state reaction at the Fe/GaSe interface.