The energy-dependent spin-density orientation (SDO) at the apex of thin mag
netic film tips is studied by spin-polarized scanning tunneling spectroscop
y (SP-STS) at different bias voltages. At most energies the SDO is collinea
r with the tip magnetization resulting in a domain or domain-wall contrast
in SP-STS images of out-of-plane magnetized samples measured with Gd or Fe
coated tips, respectively. For some bias voltages, however, the SDO of the
tip is found to be almost perpendicular to its magnetization. This result i
s explained in terms of intra-atomic noncollinear magnetism.