Synthesis and spectroscopic studies of the nicotinamide adducts of cobalt(II), nickel(II) and zinc(II) chlorides

Authors
Cakir, S Bicer, E Icbudak, H Naumov, P Korkmaz, H Cakir, O
Citation
S. Cakir et al., Synthesis and spectroscopic studies of the nicotinamide adducts of cobalt(II), nickel(II) and zinc(II) chlorides, POL J CHEM, 75(3), 2001, pp. 371-377
Citations number
16
Categorie Soggetti
Chemistry
Journal title
POLISH JOURNAL OF CHEMISTRY
ISSN journal
01375083 → ACNP
Volume
75
Issue
3
Year of publication
2001
Pages
371 - 377
Database
ISI
SICI code
0137-5083(200103)75:3<371:SASSOT>2.0.ZU;2-H
Abstract
Nicotinamide (na) adducts of Co(II), Ni(II) and Zn(II) chlorides are synthe sized and characterized by thermoanalytical methods (TG, DTG, DTA), FT IR ( 4000-400 cm(-1)) and UV/Vis spectroscopy. Structural similarity is inferred between the octahedral Co and Ni compounds of type [M(na)(2)(H2O)(4)]Cl-2. The tetrahedral Zn complex [Zn(na)(2)Cl-2] presents a different structure. The coordination of the metal ions in the Co and Ni adducts modelled by se miempirical theoretical methods compares well with the structural data for [Ni(na)(2)(H2O)(4)](NO3)(2). 2H(2)O.