APPLICATION OF TRICHLOROETHYLENE IN ORGANIC-SYNTHESIS .9. SYNTHESIS OF N-ALKYLIMINO-1,2-DI(9-CARBAZOLYL)ETHANES - EVIDENCE FOR THE MECHANISM OF THE REACTION OF DICHLOROACETYLENE WITH PRIMARY AMINES

Authors
PIELICHOWSKI J BOGDAL D
Citation
J. Pielichowski et D. Bogdal, APPLICATION OF TRICHLOROETHYLENE IN ORGANIC-SYNTHESIS .9. SYNTHESIS OF N-ALKYLIMINO-1,2-DI(9-CARBAZOLYL)ETHANES - EVIDENCE FOR THE MECHANISM OF THE REACTION OF DICHLOROACETYLENE WITH PRIMARY AMINES, Synthetic communications, 24(21), 1994, pp. 3091-3098
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
24
Issue
21
Year of publication
1994
Pages
3091 - 3098
Database
ISI
SICI code
0039-7911(1994)24:21<3091:AOTIO.>2.0.ZU;2-8
Abstract
Dichloroacetylene (C2Cl2) reacts with carbazole and primary amines und er phase-transfer catalytic (PTC) conditions to give 1-N-alkylimino-1, 2-di(9-carbazoly)ethanes (I) and 9-((E)-1,2-dichlorovinyl)carbazole (I I) in one-step synthesis. Compounds I are formed from the addition of amines to the triple bond of C2Cl2 followed by reactions with carbazol e.