X-ray diffraction studies of molecular ferrimagnet [P(C6H5)(4)][MnFe(C2O4)(3)] on heating

Authors
Shilov, GV Atovmyan, LO Ovanesyan, NS Sanina, NA
Citation
Gv. Shilov et al., X-ray diffraction studies of molecular ferrimagnet [P(C6H5)(4)][MnFe(C2O4)(3)] on heating, RUSS J C CH, 27(1), 2001, pp. 41-45
Citations number
6
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
27
Issue
1
Year of publication
2001
Pages
41 - 45
Database
ISI
SICI code
1070-3284(200101)27:1<41:XDSOMF>2.0.ZU;2-K
Abstract
A structure of the [P(C6H5)(4)][MnFe(C2O4)(3)] single crystal is studied by X-ray diffraction within the 100-370 K temperature interval. The phase tra nsition observed in the 150-170 K region is probably due to the cooperative ordering of the axial phenyl rings of the organic cations in the special p ositions.