Reaction of silver(I) with anthranilic acid and oxine

Citation
Vi. Ivlieva et al., Reaction of silver(I) with anthranilic acid and oxine, RUSS J C CH, 27(1), 2001, pp. 70-72
Citations number
5
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
27
Issue
1
Year of publication
2001
Pages
70 - 72
Database
ISI
SICI code
1070-3284(200101)27:1<70:ROSWAA>2.0.ZU;2-P
Abstract
It was found by elementary, crystal optics, X-ray diffraction analyses, and IR- and UV-spectroscopy methods that the reaction of Ag(I) with anthranili c acid (HAnt) and oxine (Ox) (at the 1 : 1 : 1 ratio of the components) yie lded a mixed-ligand complex AgOxAnt .H2O. It was shown that Ag(I) coordinat ed oxine in a neutral form and was bound with the nitrogen atom of Ox and w ith the oxygen atom of the deprotonated carboxylic group of Ant. An amino g roup of Ant(-) was not coordinated by the silver atom. The complex isolated is highly soluble in 2N solutions of nitric acid and ammonia and in concen trated sulfuric acid.