Ng. Chernorukov et Ve. Kortikov, Synthesis, structure, and properties of compounds with the general formulaA(I)[HSiUO6]center dot nH(2)O (A(I) = Rb, Cs), RUSS J IN C, 46(2), 2001, pp. 175-178
New uranosilicates Rb[HSiUO6].H2O and Cs[HSiUO6].H2O, members of the morpho
tropic series A(1/k)(k) HSiUO6. nH(2)O, were synthesized hydrothermally and
identified. The uranosilicates were characterized by X-ray diffraction, IR
spectroscopy, and thermal analysis. Their structure was studied, and therm
olysis products were identified.