[Na-4(H2O)(7)][Pe(OH)(6)Mo6O18]: a new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center

Authors
Wu, C Lin, X Yu, RM Yang, WB Lu, CZ Zhuang, HH
Citation
C. Wu et al., [Na-4(H2O)(7)][Pe(OH)(6)Mo6O18]: a new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center, SCI CHINA B, 44(1), 2001, pp. 49-54
Citations number
8
Categorie Soggetti
Chemistry
Journal title
SCIENCE IN CHINA SERIES B-CHEMISTRY
ISSN journal
1001652X → ACNP
Volume
44
Issue
1
Year of publication
2001
Pages
49 - 54
Database
ISI
SICI code
1001-652X(200102)44:1<49:[AN[MS>2.0.ZU;2-4
Abstract
The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (similar to0.184) gives rise to the formation of a six-member Mo ri ng-shape cluster with an Fe (II) encapsulated at the center, [Na-4(H2O)(7)] [Fe(OH)(6)Mo6O18](1), which is further linked to a remarkable three-dimensi onal network via sodium ions.