MARY-DETECTED ESR-SPECTRUM OF SOLVENT RADICAL CATIONS (HOLES) IN SQUALANE

Authors
TADJIKOV BM STASS DV USOV OM MOLIN YN
Citation
Bm. Tadjikov et al., MARY-DETECTED ESR-SPECTRUM OF SOLVENT RADICAL CATIONS (HOLES) IN SQUALANE, Chemical physics letters, 273(1-2), 1997, pp. 25-30
Citations number
21
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
273
Issue
1-2
Year of publication
1997
Pages
25 - 30
Database
ISI
SICI code
0009-2614(1997)273:1-2<25:MEOSRC>2.0.ZU;2-E
Abstract
The technique of magnetic field modulation of reaction yield (MARY) sp ectroscopy was employed to obtain the ESR spectrum of squalane holes t hat are formed under the action of ionizing radiation at room temperat ure. The spectrum is shown to consist of a single line which is homoge neously narrowed due to resonance charge transfer over the solvent mol ecules with the rate constant exceeding the diffusion-controlled one. (C) 1997 Published by Elsevier Science B.V.