A decanuclear oxomolybdenum(V,VI) cluster with 4-isopropylpyridine

Authors
Modec, B Brencic, JV Giester, G
Citation
B. Modec et al., A decanuclear oxomolybdenum(V,VI) cluster with 4-isopropylpyridine, ACT CRYST C, 57, 2001, pp. 246-247
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
3
Pages
246 - 247
Database
ISI
SICI code
0108-2701(200103)57:<246:ADOCW4>2.0.ZU;2-6
Abstract
The title centrosymmetric cluster octakis(4-isopropylpyridine-N)-di-mu (4)- oxo-hexa-mu (3)-oxo-octa-mu (2)-oxo-decaoxooctamolybdenum(V)dimolybdenum(VI ), [Mo10O26(C8H11N)(8)], consists of ten Mo atoms connected together by bri dging oxo groups. Pentavalent Mo atoms are linked into four Mo-2(V) pairs b y metal-metal single bonds with lengths of 2.5637 (6) and 2.6132 (6) Angstr om.