[5,10,15,20-Tetrakis(2-thienyl)-porphyrinato]zinc(II)

Authors
Purushothaman, B Varghese, B Bhyrappa, P
Citation
B. Purushothaman et al., [5,10,15,20-Tetrakis(2-thienyl)-porphyrinato]zinc(II), ACT CRYST C, 57, 2001, pp. 252-253
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
3
Pages
252 - 253
Database
ISI
SICI code
0108-2701(200103)57:<252:[>2.0.ZU;2-4
Abstract
In the title complex, [Zn(C36H20N4S4)], the Zn-II ion occupies a special po sition on an inversion centre with four-coordinate geometry. The porphyrin ring shows a wave-like conformation, with the closest interporphyrin plane separation being 3.60 (6) Angstrom. The two disordered thienyl groups are i nclined with respect to the porphyrin plane at angles of 70 (4) and 67 (2)d egrees.