Poly[copper(II)-mu-pyrazine-mu(3)-squarato]

Authors
Citation
C. Nather et I. Jess, Poly[copper(II)-mu-pyrazine-mu(3)-squarato], ACT CRYST C, 57, 2001, pp. 260-261
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
3
Pages
260 - 261
Database
ISI
SICI code
0108-2701(200103)57:<260:P>2.0.ZU;2-8
Abstract
In the structure of the title compound, [Cu(C4O4)(C4H4N2)](n), each copper cation is surrounded by three squarate (3,4-dihydroxy-3-cyclobutene-1,2-dio ate) anions and two pyrazine ligands, all of which are located in special p ositions. The copper cation and all atoms of the squarate anion are located on a mirror plane, whereas the pyrazine ligand is located around a mirror plane which is perpendicular to the ring plane. The cations are connected v ia the squarate anions and the pyrazine ligands, forming sheets parallel to (001).