Enantiomeric disorder in racemic cis-dichlorobis(pentane-2,4-dionato)-titanium(IV)

Authors
Ferguson, G Glidewell, C
Citation
G. Ferguson et C. Glidewell, Enantiomeric disorder in racemic cis-dichlorobis(pentane-2,4-dionato)-titanium(IV), ACT CRYST C, 57, 2001, pp. 264-265
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
3
Pages
264 - 265
Database
ISI
SICI code
0108-2701(200103)57:<264:EDIRC>2.0.ZU;2-A
Abstract
The title compound, [Ti(C5H7O2)(2)Cl-2], adopts the cis conrguration. The r acemic compound crystallizes in space group P (1) over bar and each molecul ar site has 0.50 occupancy by each of the two enantiomorphs. The enantiomer ic disorder is correlated in two dimensions.