trans-Bis(ethanolamine-N,O)bis-(saccharinato-N)copper(II)

Authors
Yilmaz, VT Andac, O Topcu, Y Harrison, WTA
Citation
Vt. Yilmaz et al., trans-Bis(ethanolamine-N,O)bis-(saccharinato-N)copper(II), ACT CRYST C, 57, 2001, pp. 271-272
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
3
Pages
271 - 272
Database
ISI
SICI code
0108-2701(200103)57:<271:T>2.0.ZU;2-T
Abstract
In the title complex, [Cu(C7H4NO3S)(2)(C2H7NO)(2)], the Cu-II centre lies o n an inversion centre and exhibits octahedral coordination, with the two et hanolamine (Hea) and two saccharinate [sac; anionic 1,2-benzisothiazol-3(2H )-one 1,1-dioxide] ligands in a trans configuration. The bidentate Hea liga nds bridge axial and equatorial positions and the sac anions occupy equator ial sites around the distorted octahedral copper(II) centre [Cu-O = 2.3263 (16), Cu-N-Hea = 1.9923 (16) and Cu-N-sac = 2.1776 (16) Angstrom].