(4 '-Chloro-2,2 ': 6 ',2 ''-terpyridine-N,N ',N '')(diethylphosphinothioato-S)-platinum(II) tetraphenylborate

Authors
Ross, SA Lowe, G Watkin, DJ
Citation
Sa. Ross et al., (4 '-Chloro-2,2 ': 6 ',2 ''-terpyridine-N,N ',N '')(diethylphosphinothioato-S)-platinum(II) tetraphenylborate, ACT CRYST C, 57, 2001, pp. 275-276
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
3
Pages
275 - 276
Database
ISI
SICI code
0108-2701(200103)57:<275:(''6''>2.0.ZU;2-N
Abstract
The title compound, [Pt(C4H10O3PS)(C15H10ClN3)](C24H20B), has a distorted s quare-planar coordination geometry at the platinum(II) centre, due to the c onstraints of the tridentate terpyridine ligand. The Pt-II-bound diethylpho sphinothioate ligand takes up a conformation to avoid non-bonding contacts with atoms H6 and H6 ".