We start by recalling some of the properties of hydrogen and present a summ
ary of the phenomena caused by the reversible hydrogen sorption by metals a
nd various forms of condensed carbon, at the surface and into the bulk. usi
ng molecular hydrogen gas, hydrogen plasma and electrochemically sorbed hyd
rogen. We then describe the use of hydrogen to modify the surface and bulk
properties of various materials with a focus on applications and devices: e
lectronic and optic phase transitions of thin films and related energy devi
ces, surface polishing and cleaning, decrepitation and amorphization of int
ermetallics, growth of carbon nanostructures and electron emission from dia
mond-like and graphitic carbon, longrange perturbation of the electron dist
ribution of graphitic structures by hydrogen defects, and the consequences
for potential nanoelectronics.