Influence of wavelength selection and data preprocessing on near-infrared-based classification of demolition waste

Citation
Pj. De Groot et al., Influence of wavelength selection and data preprocessing on near-infrared-based classification of demolition waste, APPL SPECTR, 55(2), 2001, pp. 173-181
Citations number
38
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
APPLIED SPECTROSCOPY
ISSN journal
00037028 → ACNP
Volume
55
Issue
2
Year of publication
2001
Pages
173 - 181
Database
ISI
SICI code
0003-7028(200102)55:2<173:IOWSAD>2.0.ZU;2-4
Abstract
The separation of demolition waste into three fractions--wood (required pur ity >90%), plastic (required purity >80%), and stone (no requirement)--has been investigated. The materials are measured with diffuse near-infrared re flectance spectroscopy and classified with linear discriminant analysis (LD A). To speed up the classification, simulated annealing extracts the six mo st discriminating wavelength regions for each preprocessing technique. For improvement in the classification results, several preprocessing techniques are investigated. Both the reflectance R and log 10(1/R) are investigated. The influence of the so-called wavelength shift (radiation that does not p ass a filter perpendicular and shifts maximally 6 nm to lower wavelength) i s accounted for during wavelength selection. preprocessing methods that rem ove spectral offset differences and remove differences in peak heights give the best classification improvement. R Modified standard normal variate (S NV) preprocessing, applied on the reflectance R, is the best preprocessing technique. The modification is the addition of the mean spectral value afte r the application of standard SNV preprocessing. The mean spectral value co ntains some additional information that is used by the (LDA) algorithm to i mprove the classification performance, The influence of the so-called wavel ength shift effect is minimal.