Pj. De Groot et al., Influence of wavelength selection and data preprocessing on near-infrared-based classification of demolition waste, APPL SPECTR, 55(2), 2001, pp. 173-181
The separation of demolition waste into three fractions--wood (required pur
ity >90%), plastic (required purity >80%), and stone (no requirement)--has
been investigated. The materials are measured with diffuse near-infrared re
flectance spectroscopy and classified with linear discriminant analysis (LD
A). To speed up the classification, simulated annealing extracts the six mo
st discriminating wavelength regions for each preprocessing technique. For
improvement in the classification results, several preprocessing techniques
are investigated. Both the reflectance R and log 10(1/R) are investigated.
The influence of the so-called wavelength shift (radiation that does not p
ass a filter perpendicular and shifts maximally 6 nm to lower wavelength) i
s accounted for during wavelength selection. preprocessing methods that rem
ove spectral offset differences and remove differences in peak heights give
the best classification improvement. R Modified standard normal variate (S
NV) preprocessing, applied on the reflectance R, is the best preprocessing
technique. The modification is the addition of the mean spectral value afte
r the application of standard SNV preprocessing. The mean spectral value co
ntains some additional information that is used by the (LDA) algorithm to i
mprove the classification performance, The influence of the so-called wavel
ength shift effect is minimal.