CRYSTAL-STRUCTURE STUDY OF CO(II) COMPLEXES WITH 2,2'-(1,4-ETHYLENEDIOXYL) DIBENZOIC ER-DOT(H2O)(3)](N)CENTER-DOT-NH(2)O-CENTER-DOT-0.2 NH(2)O

Authors
YANG G WANG L JI LN KOH LL
Citation
G. Yang et al., CRYSTAL-STRUCTURE STUDY OF CO(II) COMPLEXES WITH 2,2'-(1,4-ETHYLENEDIOXYL) DIBENZOIC ER-DOT(H2O)(3)](N)CENTER-DOT-NH(2)O-CENTER-DOT-0.2 NH(2)O, Crystal research and technology, 32(4), 1997, pp. 591-596
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Crystal research and technology → ACNP
ISSN journal
02321300
Volume
32
Issue
4
Year of publication
1997
Pages
591 - 596
Database
ISI
SICI code
0232-1300(1997)32:4<591:CSOCCW>2.0.ZU;2-7
Abstract
The structure of the title complex [Co . L .(H2O)(3)](n) . nH(2)O . 0. 2 nH(2)O has been established by single crystal X-ray diffraction. Cry stals of the complex are monoclinic, space group C2/c with cell consta nts a = 45.29(4), b = 10.631(6): c = 8.015(6) Angstrom, beta = 90.65(8 )degrees, Z = 8, D-c = 1.489 g.cm(-3). The structure was solved and re filled to R = 0.0478 (wR = 0.0577). In the ions are hexacoordinated by O atoms in an octahedral arrangement. CoO6 octahedra share corners (b ridged) through O atoms of water, with each L2--ligand binding two adj acent Co atoms.