Water solubility and diffusion in melts of commercial silicate glasses

Citation
Mg. Mesko et Je. Shelby, Water solubility and diffusion in melts of commercial silicate glasses, GL SCI T-GL, 73, 2000, pp. 13-22
Citations number
12
Categorie Soggetti
Material Science & Engineering
Journal title
GLASS SCIENCE AND TECHNOLOGY-GLASTECHNISCHE BERICHTE
ISSN journal
09467475 → ACNP
Volume
73
Year of publication
2000
Supplement
C2
Pages
13 - 22
Database
ISI
SICI code
0946-7475(2000)73:<13:WSADIM>2.0.ZU;2-F
Abstract
Water solubilities and diffusivities have been measured in melts of commerc ial (float, container, wool, E-glass, TV panel) glasses at temperatures ran ging from 900 to 1400 degreesC. The solubility of water in these melts is e ssentially independent of temperature, with values lying between 1000 and 1 200 wtppm for the float, container, wool, and E-glass melts and at approxim ately 1600 wtppm for the TV panel melts. The diffusivity of water for all m elts lies increases with increasing temperature, with values between 5 x 10 (-7) and 5 x 10(-5) cm(2)/s for all melts. While an apparent correlation ca n be made between the diffusivity of water and the viscosity of the melt, t his correlation cannot be taken as proof that such a correlation is a gener al phenomenon.