Mg. Krishna et Ak. Bhattacharya, Quantum confinement effects on the optical properties of ion beam sputtered nickel oxide thin films, INT J MOD B, 15(2), 2001, pp. 191-200
Quantum confinement effects on the optical properties of ion beam sputtered
nickel oxide thin films are reported. Thin films with crystallite sizes in
the range 9 to 14 nm have been deposited on to fused silica substrates. Th
ere is an increase in band gap, from 3.4 to 3.9 eV, and a decrease in refra
ctive index, from 2.4 to 1.8, with decrease in crystallite size, that can b
e attributed to quantum confinement effects. The effective mass approximati
on has been used to explain the observed behaviour in band gap variation.