G. Rixecker et R. Haberkorn, Fe16Nb6Si7 and Fe16Ta6Si7: New D8(a) phases synthesized by the crystallization of mechanically alloyed amorphous powders, J ALLOY COM, 316(1-2), 2001, pp. 203-208
Ternary phases with the cubic D8(a) structure (isostructural to Mg16Cu6Si7)
were identified in both the Fe-Nb-Si and Fe-Ta-Si systems. They form durin
g the crystallization of mechanically alloyed amorphous materials and are t
hermally stable during heat treatments up to 90 h at 1050 degreesC. The X-r
ay powder diffraction data were evaluated (i) by local line fit, and (ii) b
y Rietveld analysis. Mossbauer spectroscopy was used to complement the XRD
results and to show the absence of magnetic ordering above 77 K. (C) 2001 E
lsevier Science B.V. All rights reserved.