The properties of vanadium-titanium oxide catalysts, which contain coherent
phase boundaries formed by V2O5 and TiO2 crystallites during reduction by
hydrogen at 150-500 degreesC, are examined. The phase boundary is preserved
over the entire examined temperature range regardless of the structure of
vanadium oxide, which is formed. The state of vanadium ions at the phase bo
undary is determined. The presence of a phase boundary in the catalyst is r
esponsible for the V2O5 --> V2O3 transition without the formation of interm
ediate structures.