Vg. Nazarenko et al., Non-Debye charge screening and adsorbed-ion-induced anchoring transition in a nematic liquid crystal, MOLEC CRYST, 352, 2000, pp. 435-442
Anchoring transition mechanism due to substrate-adsorbed ions is studied. I
t is shown that the surface field is screened by a very dense charged subsu
rface layer whose thickness lambda (S) is much smaller than the Debye lengt
h lambda (D). It is shown both theoretically and experimentally that critic
al temperature of the transition can be controlled by bulk ion density thro
ugh its relation to the density of adsorbed ions.