Phase diagram of confined antiferroelectric liquid crystals in an electricfield

Citation
Tz. Qian et Pl. Taylor, Phase diagram of confined antiferroelectric liquid crystals in an electricfield, MOLEC CRYST, 351, 2000, pp. 229-236
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
351
Year of publication
2000
Pages
229 - 236
Database
ISI
SICI code
Abstract
We study the electric-field-induced transitions in antiferroelectric liquid crystals in a model that takes into account the intralayer elastic distort ion, the nearest-neighbor interlayer interaction, the coupling of the spont aneous polarization with the applied field, the dielectric anisotropy, and the surface anchoring. We find that the field-induced phase sequence has a critical dependence on cell thickness. For moderately thin cells (thickness > 0.1 mum) with moderately strong anchoring (surface coupling similar to 1 0(-4) J/m(2)), the system, in departing from the initial anticlinic alignme nt, first undergoes a continuous Freederiksz transition, then a first-order surface boundary-layer transition, and finally a first-order or continuous transition to a complete synclinic ordering. Reducing the cell thickness t o less than 0.1 mum will make the Freedericksz transition and even the boun dary-layer transition vanish.