C-H and C-C bond activation of primary amines through dehydrogenation and transimination

Authors
Jun, CH Chung, KY Hong, JB
Citation
Ch. Jun et al., C-H and C-C bond activation of primary amines through dehydrogenation and transimination, ORG LETT, 3(5), 2001, pp. 785-787
Citations number
36
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
5
Year of publication
2001
Pages
785 - 787
Database
ISI
SICI code
1523-7060(20010308)3:5<785:CACBAO>2.0.ZU;2-S
Abstract
[GRAPHICS] Dehydrogenation and subsequent transimination of primary amines offer a new pathway for C-H bond activation, ortho-alkylation, and C-C bond activation to afford a variety of ketones in the reaction of l-alkene by a cocatalyt system of Rh(I) and 2-amino-3-picoline.